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Scientific article
English

A short, stereodivergent synthesis of the racemic erythro and threo diastereomers of 6-acetoxy-5-hexadecanolide, a mosquito oviposition attractant pheromone

Published inTetrahedron letters, vol. 27, no. 34, p. 4011-4014
Publication date1986
Abstract

A versatile 3-step synthesis of the title lactones has been accomplished by the stereocontrolled addition of n-decylmetallic reagents to acrolein dimer. Stereocontrol of the first step enables selective synthesis of either diastereomeric lactone.

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Citation (ISO format)
JEFFORD, Charles, JAGGI, Danielle, BOUKOUVALAS, John. A short, stereodivergent synthesis of the racemic erythro and threo diastereomers of 6-acetoxy-5-hexadecanolide, a mosquito oviposition attractant pheromone. In: Tetrahedron letters, 1986, vol. 27, n° 34, p. 4011–4014. doi: 10.1016/S0040-4039(00)84897-2
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ISSN of the journal0040-4039
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