Proceedings chapter
English

Selective Reactions on Arene Chromium Complexes

Presented atFirst Symposium on "Organic Synthesis via Organometallics", Hamburg, 4-8.2.1987
Published inMeijere, Armin de & Dieck, Heindrick (Ed.), Organometallics in organic synthesis : aspects of a modern interdisciplinary field, p. 265-276
PublisherBerlin : Springer
Publication date1987
Abstract

Arene complexes of transition metals figure prominently in the field of organometallic chemistry (Collman, 1987; Watts, 1982). This, in part, is due to the rich structural, stereochemical and electronic features of arene metal bonds (Muetterties, 1982). It is also due to the ability of coordinated arenes to undergo new and highly selective reactions under mild conditions. In preparative organic chemistry, arene transformations via complexation complement classic arene chemistry such as aromatic electrophilic substitution (Collman, 1987) (Watts, 1982; Muetterties, 1982; Braun, 1985). Particularly useful in this respect are those arene complexes in which the arene is bound to electron withdrawing fragments.

Keywords
  • Arene Complex
  • Aromatic Electrophilic Substitution
  • Arene Exchange
  • Arene Ligand
  • Carbon Electrophile
Citation (ISO format)
KUNDIG, Ernst Peter et al. Selective Reactions on Arene Chromium Complexes. In: Organometallics in organic synthesis : aspects of a modern interdisciplinary field. Meijere, Armin de & Dieck, Heindrick (Ed.). Hamburg. Berlin : Springer, 1987. p. 265–276. doi: 10.1007/978-3-642-73196-9_14
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ISBN978-3-540-18592-5
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