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Scientific article
English

Enantioselective synthesis of sec-allylalcohols by catalytic asymmetric addition of divinylzinc to aldehydes

Published inTetrahedron letters, vol. 29, no. 44, p. 5645-5648
Publication date1988
Abstract

Readily available chiral tridentate ligand 8 catalyzes the highly Si-face selective addition of diethyl-, di-n-propylzinc and, more significantly, of divinylzinc to aromatic and aliphatic aldehydes whereas bidentate ligands 11 and 12 exert a topologically reversed catalytic bias.

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Citation (ISO format)
VON OPPOLZER, Wolfgang, RADINOV, Roumen Nikolaev. Enantioselective synthesis of <i>sec</i>-allylalcohols by catalytic asymmetric addition of divinylzinc to aldehydes. In: Tetrahedron letters, 1988, vol. 29, n° 44, p. 5645–5648. doi: 10.1016/S0040-4039(00)80834-5
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ISSN of the journal0040-4039
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