Electronic control of the stereoselectivities of electrocyclic reactions of cyclobutenes against incredible steric odds

Houk, K.N.; Spellmeyer, David C.; Jefford, Charles; Rimbault, Christian G.; Wang, Ying; Miller, R.D.

doi:10.1021/jo00244a058

Scientific article

English

Electronic control of the stereoselectivities of electrocyclic reactions of cyclobutenes against incredible steric odds

ContributorsHouk, K.N.; Spellmeyer, David C.; Jefford, Charles; Rimbault, Christian G.; Wang, Ying; Miller, R.D.

Published inJournal of organic chemistry, vol. 53, no. 9, p. 2125-2127

Publication date1988

First online date2002-05-01

Abstract

Experimental studies of the electrocyclic reactions of 2- and 3-tert-butyl-3-(trimethylsiloxy)cyclobutene and of 3-methoxy-3-fert-butylcyclobutene confirm ab initio computational predictions.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

HOUK, K.N. et al. Electronic control of the stereoselectivities of electrocyclic reactions of cyclobutenes against incredible steric odds. In: Journal of organic chemistry, 1988, vol. 53, n° 9, p. 2125–2127. doi: 10.1021/jo00244a058

Article (Published version)

Identifiers

PID : unige:166469
DOI : 10.1021/jo00244a058

Additional URL for this publicationhttps://pubs.acs.org/doi/abs/10.1021/jo00244a058

Journal ISSN0022-3263

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Electronic control of the stereoselectivities of electrocyclic reactions of cyclobutenes against incredible steric odds

Experimental studies of the electrocyclic reactions of 2- and 3-tert-butyl-3-(trimethylsiloxy)cyclobutene and of 3-methoxy-3-fert-butylcyclobutene confirm ab initio computational predictions.

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