Efficient Preparation of 1,2,4,5-Tetroxanes from Bis(trimethylsilyl) Peroxide and Carbonyl Compounds

Jefford, Charles; Jaber, Amer; Boukouvalas, John

doi:10.1055/s-1988-27586

Scientific article

English

Efficient Preparation of 1,2,4,5-Tetroxanes from Bis(trimethylsilyl) Peroxide and Carbonyl Compounds

ContributorsJefford, Charles; Jaber, Amer; Boukouvalas, John

Published inSynthesis, vol. 5, no. 5, p. 391-393

Publication date1988

Abstract

Symmetrically 3,6-disubstituted and 3,3,6,6-tetrasubstituted 1,2,4,5-tetroxanes are prepared in good yields by the condensation of bis(trimethylsilyl) peroxide with aldehydes and ketones in the presence of trimethylsilyl trifluoromethanesulfonate.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

JEFFORD, Charles, JABER, Amer, BOUKOUVALAS, John. Efficient Preparation of 1,2,4,5-Tetroxanes from Bis(trimethylsilyl) Peroxide and Carbonyl Compounds. In: Synthesis, 1988, vol. 5, n° 5, p. 391–393. doi: 10.1055/s-1988-27586

Article (Published version)

Identifiers

PID : unige:166467
DOI : 10.1055/s-1988-27586

Additional URL for this publicationhttp://www.thieme-connect.de/DOI/DOI?10.1055/s-1988-27586

Journal ISSN0039-7881

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Efficient Preparation of 1,2,4,5-Tetroxanes from Bis(trimethylsilyl) Peroxide and Carbonyl Compounds

Symmetrically 3,6-disubstituted and 3,3,6,6-tetrasubstituted 1,2,4,5-tetroxanes are prepared in good yields by the condensation of bis(trimethylsilyl) peroxide with aldehydes and ketones in the presence of trimethylsilyl trifluoromethanesulfonate.

Technical informations