Oxidation of amines to imines with hypervalent iodine

Muller, Paul; Gilabert, David Manuel

doi:10.1016/S0040-4020(01)86085-3

Scientific article

English

Oxidation of amines to imines with hypervalent iodine

ContributorsMuller, Paul; Gilabert, David Manuel

Published inTetrahedron, vol. 44, no. 23, p. 7171-7175

Publication date1988

Abstract

PhIO, either atone or in conjunction with RuCl₂(PPh₃)₃ is efficient for dehydrogenation of secondary, activated amines to imines. PhIO also effects oxidative decarboxylation of phenylalanine ethyl ester to benzyl cyanide. The mechanistic significance of this latter transformation, which does not occur with other hypervalent iodine oxidants is discussed.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

MULLER, Paul, GILABERT, David Manuel. Oxidation of amines to imines with hypervalent iodine. In: Tetrahedron, 1988, vol. 44, n° 23, p. 7171–7175. doi: 10.1016/S0040-4020(01)86085-3

Article (Published version)

Identifiers

PID : unige:166454
DOI : 10.1016/S0040-4020(01)86085-3

Additional URL for this publicationhttps://linkinghub.elsevier.com/retrieve/pii/S0040402001860853

Journal ISSN0040-4020

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Oxidation of amines to imines with hypervalent iodine

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