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Scientific article
English

Oxidation of amines to imines with hypervalent iodine

Published inTetrahedron, vol. 44, no. 23, p. 7171-7175
Publication date1988
Abstract

PhIO, either atone or in conjunction with RuCl2(PPh3)3 is efficient for dehydrogenation of secondary, activated amines to imines. PhIO also effects oxidative decarboxylation of phenylalanine ethyl ester to benzyl cyanide. The mechanistic significance of this latter transformation, which does not occur with other hypervalent iodine oxidants is discussed.

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Citation (ISO format)
MULLER, Paul, GILABERT, David Manuel. Oxidation of amines to imines with hypervalent iodine. In: Tetrahedron, 1988, vol. 44, n° 23, p. 7171–7175. doi: 10.1016/S0040-4020(01)86085-3
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ISSN of the journal0040-4020
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