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Scientific article
English

Reactions of Trienals Catalyzed by Chiral Ruthenium Lewis Acids

Published inChimia, vol. 65, no. 4, p. 268-270
Publication date2011
Abstract

Chiral single-point binding ruthenium Lewis acid catalysts [Ru(acetone)((S,S)-BIPHOP-F)(Cp)][SbF6]((S,S)-1a) and [Ru(acetone)((S,S)-BIPHOP-F)(indenyl)][SbF6] ((S,S)-1b) efficiently catalyze intramolecular DielsAlder (IMDA) reactions of trienals under mild conditions to afford the endo cycloaddition products as the major products in good yields with high diastereo- and enantioselectivities.

Keywords
  • Asymmetric IMDA reaction
  • Chiral catalyst
  • Diels-Alder
  • Lewis acid
  • Ruthenium
Citation (ISO format)
THAMAPIPOL, Sirinporn, KUNDIG, Ernst Peter. Reactions of Trienals Catalyzed by Chiral Ruthenium Lewis Acids. In: Chimia, 2011, vol. 65, n° 4, p. 268–270. doi: 10.2533/chimia.2011.268
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Article (Published version)
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Identifiers
ISSN of the journal0009-4293
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Technical informations

Creation06/20/2011 10:08:00 AM
First validation06/20/2011 10:08:00 AM
Update time03/14/2023 4:52:21 PM
Status update03/14/2023 4:52:21 PM
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