Heteroleptic mer -[Cr(N ∩ N ∩ N)(CN)<sub>3</sub>] complexes: synthetic challenge, structural characterization and photophysical properties

CHONG, Julien et al. Heteroleptic mer -[Cr(N ∩ N ∩ N)(CN)₃] complexes: synthetic challenge, structural characterization and photophysical properties. In: Dalton transactions, 2022, vol. 51, n° 11, p. 4297–4309. doi: 10.1039/d2dt00126h

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PID : unige:160292
DOI : 10.1039/d2dt00126h
PMID : 35195140

Commercial URLhttp://xlink.rsc.org/?DOI=D2DT00126H

ISSN of the journal1477-9226

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Heteroleptic mer -[Cr(N ∩ N ∩ N)(CN)3] complexes: synthetic challenge, structural characterization and photophysical properties

The heteroleptic mer-[Cr(L)(CN) 3 ] (L = tpy, ddpd, dqp) complexes with their C 2v -symmetrical [CrC 3 N 3 ] luminescent chromophores represent the missing links between pseudo-octahedral [CrN 6 ] and [CrC 6 ] units found in their well-known homoleptic parents.

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Heteroleptic mer -[Cr(N ∩ N ∩ N)(CN)₃] complexes: synthetic challenge, structural characterization and photophysical properties

The heteroleptic mer-[Cr(L)(CN) ₃ ] (L = tpy, ddpd, dqp) complexes with their C _2v -symmetrical [CrC ₃ N ₃ ] luminescent chromophores represent the missing links between pseudo-octahedral [CrN ₆ ] and [CrC ₆ ] units found in their well-known homoleptic parents.