Scientific article
English

Thorium colloid analysis by single particle inductively coupled plasma-mass spectrometry

Published inTalanta, vol. 62, p. 1051-1054
Publication date2003-10-14
Abstract

Thorium colloid analysis in water has been carried out by a single particle mode using inductively coupled plasma mass spectrometry (ICP-MS). The flash of ions due to the ionisation of a thorium colloidal particle in the plasma torch can be detected and measured in a time scan for ²³²Th⁺ or ²⁴⁸[ThO]⁺ according to the sensitivity required by the mass spectrometer. The peaks of the recorded intensity of the MS signal can be analysed as a function of the particle size or fraction of the studied element in the colloid phase. The frequency of the flashes is directly proportional to the concentration of particles in the colloidal suspension. After discussing Th colloid detection, on the basis of the intensity of the ion flashes generated in the plasma torch, tests were performed on thorium dioxide colloidal particles. This feasibility study also describes the experimental conditions and the limitation of the plasma design to detect thorium colloids in a single particle analysis mode down to about 10 fg.

Keywords
  • Single particle analysis
  • ICP-MS
  • Thorium colloid
  • Colloid size
Citation (ISO format)
DEGUELDRE, Claude, FAVARGER, Pierre-Yves. Thorium colloid analysis by single particle inductively coupled plasma-mass spectrometry. In: Talanta, 2003, vol. 62, p. 1051–1054. doi: 10.1016/j.talanta.2003.10.016
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Identifiers
Journal ISSN0039-9140
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