Die Addition von Fluorcarbenen an Norbornadien: eine Homo-1,4-addition

Jefford, Charles; Kabengele, Ntanda; Kovacs, Josef; Burger, Ulrich

doi:10.1002/hlca.19740570110

Scientific article

German

Die Addition von Fluorcarbenen an Norbornadien: eine Homo-1,4-addition

ContributorsJefford, Charles; Kabengele, Ntanda; Kovacs, Josef; Burger, Ulrich

Published inHelvetica chimica acta, vol. 57, no. 1, p. 104-113

Publication date1974

Abstract

It has been found that difluorocarbene undergoes extensive addition to the endo-face of norbornadiene, yeilding the cheletropic adduct, 4.4-difluorotetracyclo[3.3.0.02,8.03,6]-octane. Similar behaviour has been observed for fluorochlorocarbene. Possible mechanisms to rationalize this novel behaviour of carbenes are discussed.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

JEFFORD, Charles et al. Die Addition von Fluorcarbenen an Norbornadien: eine Homo-1,4-addition. In: Helvetica chimica acta, 1974, vol. 57, n° 1, p. 104–113. doi: 10.1002/hlca.19740570110

Article (Published version)

Identifiers

PID : unige:159241
DOI : 10.1002/hlca.19740570110

Additional URL for this publicationhttps://onlinelibrary.wiley.com/doi/10.1002/hlca.19740570110

Journal ISSN0018-019X

142views

0downloads

Creation28/02/2022 13:41:00

First validation28/02/2022 13:41:00

Update time16/03/2023 02:45:31

Status update16/03/2023 02:45:30

Last indexation01/11/2024 01:00:33

Archive ouverte UNIGE

Die Addition von Fluorcarbenen an Norbornadien: eine Homo-1,4-addition

Technical informations