Article (Published version) (315 Kb) - 
Limited access to UNIGEOther version: http://doi.wiley.com/10.1002/anie.201100804
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Scientific Article
unige:15871 
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Asymmetric Organocatalytic 1,6-Conjugate Addition of Aldehydes to Dienic Sulfones |
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| Authors | ||
| Published in | Angewandte Chemie: International Edition. 2011, vol. 50, no. 22, p. 5095-5098 | |
| Abstract | An unprecedented 1,6-enamine conjugate addition exploiting the charge delocalization in 1,3-bis(sulfonyl) butadienes has been developed. By appropriately designing a Michael acceptor, unique reactivities were obtained for the formation of highly valuable dienes containing two versatile vinyl sulfones (see scheme, TMS=trimethylsilyl). | |
| Keywords | Asymmetric synthesis — Conjugate addition — Dienes — Organocatalysis — Sulfones | |
| Stable URL | https://archive-ouverte.unige.ch/unige:15871 | |
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Article (Published version) (315 Kb) - Limited access to UNIGE Other version: http://doi.wiley.com/10.1002/anie.201100804 |
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