UNIGE document Scientific Article
previous document  unige:15871  next document
add to browser collection
Title

Asymmetric Organocatalytic 1,6-Conjugate Addition of Aldehydes to Dienic Sulfones

Authors
Murphy, John J.
McArdle, Patrick
Stephens, John C.
Published in Angewandte Chemie: International Edition. 2011, vol. 50, no. 22, p. 5095-5098
Abstract An unprecedented 1,6-enamine conjugate addition exploiting the charge delocalization in 1,3-bis(sulfonyl) butadienes has been developed. By appropriately designing a Michael acceptor, unique reactivities were obtained for the formation of highly valuable dienes containing two versatile vinyl sulfones (see scheme, TMS=trimethylsilyl).
Keywords Asymmetric synthesisConjugate additionDienesOrganocatalysisSulfones
Stable URL https://archive-ouverte.unige.ch/unige:15871
Full text
Article (Published version) (315 Kb) - document accessible for UNIGE members only Limited access to UNIGE
Other version: http://doi.wiley.com/10.1002/anie.201100804
Identifiers
Structures

223 hits

5 downloads

Update

Deposited on : 2011-05-24

Export document
Format :
Citation style :