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Title

Asymmetric Organocatalytic 1,6-Conjugate Addition of Aldehydes to Dienic Sulfones
Authors
Murphy, John J.
Quintard, Adrien
McArdle, Patrick
Alexakis, Alexandre
Stephens, John C.
Published in Angewandte Chemie: International Edition. 2011, vol. 50, no. 22, p. 5095-5098
Abstract An unprecedented 1,6-enamine conjugate addition exploiting the charge delocalization in 1,3-bis(sulfonyl) butadienes has been developed. By appropriately designing a Michael acceptor, unique reactivities were obtained for the formation of highly valuable dienes containing two versatile vinyl sulfones (see scheme, TMS=trimethylsilyl).
Keywords Asymmetric synthesis — Conjugate addition — Dienes — Organocatalysis — Sulfones
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Article (Published version) (315 Kb) - document accessible for UNIGE members only Limited access to UNIGE
Structures
Faculté des sciences / Section de chimie et biochimie / Département de chimie organique
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(ISO format) 		MURPHY, John J. et al. Asymmetric Organocatalytic 1,6-Conjugate Addition of Aldehydes to Dienic Sulfones. In: Angewandte Chemie: International Edition, 2011, vol. 50, n° 22, p. 5095-5098. doi: 10.1002/anie.201100804 https://archive-ouverte.unige.ch/unige:15871

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Deposited on : 2011-05-24

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