Absolute configuration retention of a configurationally labile ligand during dynamic processes of thiolate protected gold clusters

WANG, Yanan et al. Absolute configuration retention of a configurationally labile ligand during dynamic processes of thiolate protected gold clusters. In: Chemical science, 2021, vol. 12, n° 27, p. 9413–9419. doi: 10.1039/D1SC01702K

Article (Published version)

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Identifiers

PID : unige:157887
DOI : 10.1039/D1SC01702K
PMID : 34349915
PMCID : PMC8278927

Additional URL for this publicationhttp://xlink.rsc.org/?DOI=D1SC01702K

Journal ISSN2041-6520

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Creation11/01/2022 13:46:00

First validation11/01/2022 13:46:00

Update16/03/2023 02:20:12

Status update16/03/2023 02:20:11

Last indexation01/11/2024 00:26:40

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Absolute configuration retention of a configurationally labile ligand during dynamic processes of thiolate protected gold clusters

The ligand exchange between a configurationally labile BiDi ligand and intrinsically chiral Au 38 gold nanoclusters is diastereoselective. More importantly, the adsorbed ligand retains its configuration during dynamic cluster processes.

Technical informations

The ligand exchange between a configurationally labile BiDi ligand and intrinsically chiral Au ₃₈ gold nanoclusters is diastereoselective. More importantly, the adsorbed ligand retains its configuration during dynamic cluster processes.