Thomas Bally has acquired international recognition for his work on the photochemistry of reactive intermediates, which include radical ions. Here, we present a brief overview of our investigations of the excited-state dynamics of radical ions in liquids at room temperature, which are still poorly documented. A better understanding of these dynamics is most relevant, as open-shell ions in the excited state are being increasingly used in redox photochemistry and have been proposed to play a key role in highly exergonic photoinduced electron transfer reactions.