Synthesis of (-)-erythrodiene via intramolecular Pd-catalyzed Zn-ene reaction

Von Oppolzer, Wolfgang; Flachsmann, Félix

doi:10.1016/s0040-4039(98)00991-5

Article scientifique

Anglais

Synthesis of (-)-erythrodiene via intramolecular Pd-catalyzed Zn-ene reaction

Contributeurs/tricesVon Oppolzer, Wolfgang; Flachsmann, Félix

Publié dansTetrahedron letters, vol. 39, no. 28, p. 5019-5022

Date de publication1998-07-09

Date de mise en ligne1998-08-17

Résumé

A highly diastereoselective synthesis of (-)-Erythrodiene was achieved via an intrantolecular Pd-catalyzed Zn-ene reaction as the key step. It was found that Pd(OAc)2/Bu3P was a superior catalyst for this reaction to Pd(PPh3)4.

Structure d'affiliation

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (format ISO)

VON OPPOLZER, Wolfgang, FLACHSMANN, Félix. Synthesis of (-)-erythrodiene via intramolecular Pd-catalyzed Zn-ene reaction. In: Tetrahedron letters, 1998, vol. 39, n° 28, p. 5019–5022. doi: 10.1016/s0040-4039(98)00991-5

Article (Published version)

Identifiants

PID : unige:155659
DOI : 10.1016/s0040-4039(98)00991-5

URL commercialhttps://linkinghub.elsevier.com/retrieve/pii/S0040403998009915

ISSN du journal0040-4039

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Création13.10.2021 12:21:00

Première validation13.10.2021 12:21:00

Heure de mise à jour16.03.2023 01:35:34

Changement de statut16.03.2023 01:35:33

Dernière indexation29.01.2024 22:50:14

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Synthesis of (-)-erythrodiene via intramolecular Pd-catalyzed Zn-ene reaction

A highly diastereoselective synthesis of (-)-Erythrodiene was achieved via an intrantolecular Pd-catalyzed Zn-ene reaction as the key step. It was found that Pd(OAc)2/Bu3P was a superior catalyst for this reaction to Pd(PPh3)4.

Informations techniques