Synthesis of (-)-erythrodiene via intramolecular Pd-catalyzed Zn-ene reaction

Von Oppolzer, Wolfgang; Flachsmann, Félix

doi:10.1016/s0040-4039(98)00991-5

Scientific article

English

Synthesis of (-)-erythrodiene via intramolecular Pd-catalyzed Zn-ene reaction

ContributorsVon Oppolzer, Wolfgang; Flachsmann, Félix

Published inTetrahedron letters, vol. 39, no. 28, p. 5019-5022

Publication date1998-07-09

First online date1998-08-17

Abstract

A highly diastereoselective synthesis of (-)-Erythrodiene was achieved via an intrantolecular Pd-catalyzed Zn-ene reaction as the key step. It was found that Pd(OAc)2/Bu3P was a superior catalyst for this reaction to Pd(PPh3)4.

Affiliation

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

VON OPPOLZER, Wolfgang, FLACHSMANN, Félix. Synthesis of (-)-erythrodiene via intramolecular Pd-catalyzed Zn-ene reaction. In: Tetrahedron letters, 1998, vol. 39, n° 28, p. 5019–5022. doi: 10.1016/s0040-4039(98)00991-5

Article (Published version)

Identifiers

PID : unige:155659
DOI : 10.1016/s0040-4039(98)00991-5

Commercial URLhttps://linkinghub.elsevier.com/retrieve/pii/S0040403998009915

ISSN of the journal0040-4039

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Synthesis of (-)-erythrodiene via intramolecular Pd-catalyzed Zn-ene reaction

A highly diastereoselective synthesis of (-)-Erythrodiene was achieved via an intrantolecular Pd-catalyzed Zn-ene reaction as the key step. It was found that Pd(OAc)2/Bu3P was a superior catalyst for this reaction to Pd(PPh3)4.

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