Scientific article
English

Formation of the stress-induced mm2 phase at the ferroelastic-antiferroelectric-phase transition in Cr-Cl boracite

Published inJournal of Physics. Condensed Matter, vol. 8, no. 33, p. 6087-6094
Publication date1996
Abstract

Experimental and crystallographic investigations of the formation of the mm2 phase induced by internal stress at the - phase boundaries during the first-order ferroelastic - antiferroelectric phase transition in boracite crystals are presented. Different possibilities are demonstrated, by means of the determination of zero-net-strain planes, for the transformation from the tetragonal or the cubic phase to the orthorhombic one. The formation of the mm2 phase results in stress relief at the mechanically non-matching - interfaces. Such a compromise role of the mm2 phase permits us to understand the mechanism of the stress-induced phase transition and the three-phase coexistence.

Citation (ISO format)
TOPOLOV, V Yu, YE, Zuo-Guang. Formation of the stress-induced mm2 phase at the ferroelastic-antiferroelectric-phase transition in Cr-Cl boracite. In: Journal of Physics. Condensed Matter, 1996, vol. 8, n° 33, p. 6087–6094. doi: 10.1088/0953-8984/8/33/015
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Journal ISSN0953-8984
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