Synthesis of 1H-Cyclopropal[g]quinoline via Trapping of an ortho-Quinodimethane

Muller, Paul; Schaller, Jean-Pierre

doi:10.1002/hlca.19900730512

Scientific article

English

Synthesis of 1H-Cyclopropal[g]quinoline via Trapping of an ortho-Quinodimethane

ContributorsMuller, Paul; Schaller, Jean-Pierre

Published inHelvetica Chimica Acta, vol. 73, no. 5, p. 1228-1232

Publication date1990

Abstract

1H-Cyclopropa[g]quinoline (3-aza-lH-cyclopropa[b]naphthalene; 17) was synthesized via interception of the heterocyclic ortho -quinodimethane 15 with l-bromo-2-chlorocyclopropene, followed by aromatization of the adduct 16 with t-BuOK.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Funding

Swiss National Science Foundation - 2.602-0.87

Citation (ISO format)

MULLER, Paul, SCHALLER, Jean-Pierre. Synthesis of 1H-Cyclopropal[g]quinoline via Trapping of an ortho-Quinodimethane. In: Helvetica Chimica Acta, 1990, vol. 73, n° 5, p. 1228–1232. doi: 10.1002/hlca.19900730512

Article (Published version)

Identifiers

PID : unige:152914
DOI : 10.1002/hlca.19900730512

Additional URL for this publicationhttps://onlinelibrary.wiley.com/doi/10.1002/hlca.19900730512

Journal ISSN0018-019X

213views

0downloads

Creation08/07/2021 09:05:00

First validation08/07/2021 09:05:00

Update time16/03/2023 00:52:40

Status update16/03/2023 00:52:40

Last indexation31/10/2024 22:31:42

Archive ouverte UNIGE

Synthesis of 1H-Cyclopropal[g]quinoline via Trapping of an ortho-Quinodimethane

1H-Cyclopropa[g]quinoline (3-aza-lH-cyclopropa[b]naphthalene; 17) was synthesized via interception of the heterocyclic ortho -quinodimethane 15 with l-bromo-2-chlorocyclopropene, followed by aromatization of the adduct 16 with t-BuOK.

Technical informations