Article (Published version) (635 Kb) - 
Limited access to UNIGEOther version: https://onlinelibrary.wiley.com/doi/10.1107/S0108270189014356
Highlights
Home
Titles listStructure of Synthetic Bromobeckerelide: a Case of Diastereomeric Selection in the Solid State
Titles listStructure of Synthetic Bromobeckerelide: a Case of Diastereomeric Selection in the Solid State
Scientific Article
unige:152908 
 |
Structure of Synthetic Bromobeckerelide: a Case of Diastereomeric Selection in the Solid State |
|
| Authors | ||
| Published in | Acta crystallographica. Section C, Crystal structure communications. 1990, vol. 46, no. 10, p. 1879-1881 | |
| Abstract | 4-Bromo-5-hydroxy-3-(1-hydroxybutyl)-5- methyl-5H-furan-2-0ne, C₉H₁₃BrO₄, recrystallized from CH₂Cl₂/hexane, m.p. 359-360 K, Mr = 265.1, triclinic, P1, a=5.9067 (4), b=9.4807 (9), c=11.0895(11)Å, α=74.16(1), β=79.96(1), γ=71.87 (1) °, V=565.1 (1)ų, Z=2, F(000)=268, Dx=1.56 Mg m⁻³, λ(Mo Kα)=0.71069 Å, μ=3.59mm⁻¹, room temperature, R=0.044 [wR=0.043, w = l/σ²(F₀)] for 1273 observed reflections [|Fo| > 4σ(F₀)]. In the solid state, which is different from the situation in solution, only the diastereomer having the like configuration is observed. Molecules of the same configuration are linked by hydrogen bonds involving both hydroxyl groups of the same molecule. | |
| Identifiers | ||
| Full text |
Article (Published version) (635 Kb) - Limited access to UNIGE Other version: https://onlinelibrary.wiley.com/doi/10.1107/S0108270189014356 |
|
| Structures | ||
| Citation (ISO format) | JEFFORD, Charles et al. Structure of Synthetic Bromobeckerelide: a Case of Diastereomeric Selection in the Solid State. In: Acta Crystallographica. C, Crystal Structure Communications, 1990, vol. 46, n° 10, p. 1879-1881. doi: 10.1107/S0108270189014356 https://archive-ouverte.unige.ch/unige:152908 |
74 hits 
0 download 
Contact an author
Update