Detection of Carbonyl Oxide from Singlet <i>p</i>-Nitrophenylchlorocarbene and Oxygen

Liu, Michael T.H.; Bonneau, Roland; Jefford, Charles

doi:10.1039/c39900001482

Scientific article

English

Detection of Carbonyl Oxide from Singlet p-Nitrophenylchlorocarbene and Oxygen

ContributorsLiu, Michael T.H.; Bonneau, Roland; Jefford, Charles

Published inJournal of the Chemical Society. Chemical Communications, no. 21, p. 1482-1483

Publication date1990

Abstract

p-Nitrophenylchlorocarbene reacts with oxygen with a rate constant 2.24×10⁷M⁻¹S⁻¹ in isooctane at 25 °C giving rise to an intermediate carbonyl oxide which absorbs at 400 nm.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

LIU, Michael T.H., BONNEAU, Roland, JEFFORD, Charles. Detection of Carbonyl Oxide from Singlet p-Nitrophenylchlorocarbene and Oxygen. In: Journal of the Chemical Society. Chemical Communications, 1990, n° 21, p. 1482–1483. doi: 10.1039/c39900001482

Article (Published version)

Identifiers

PID : unige:152905
DOI : 10.1039/c39900001482

Additional URL for this publicationhttp://xlink.rsc.org/?DOI=c39900001482

Journal ISSN0022-4936

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Detection of Carbonyl Oxide from Singlet p-Nitrophenylchlorocarbene and Oxygen

p-Nitrophenylchlorocarbene reacts with oxygen with a rate constant 2.24×10⁷M⁻¹S⁻¹ in isooctane at 25 °C giving rise to an intermediate carbonyl oxide which absorbs at 400 nm.

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