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Scientific article
Letter
English

The pseudo-enzymatic action of tri-o-thymotide clathrates applied to the determination of the absolute configuration of four halohydrins

Published inTetrahedron Letters, vol. 30, no. 48, p. 6677-6678
Publication date1989
Abstract

The heterogeneous reactions of gaseous HCl and HBr, as external agents, with trans-2,3-dimethyloxirane and 2,2,3-trimethyloxirane as guest molecules in tri-o-thymotide clathrates are shown to allow the ready determination of the absolute configuration of the end-products owing to highly specific host-reactant interactions. Heterogenous reactions of hydrogenhalides (gas) with TOT-enclathrated methyloxiranes allow the absolute configuration assignment of the product owing to highly specific host-reactant interactions.

Citation (ISO format)
GERDIL, Raymond, BARCHIETTO, Giacomo. The pseudo-enzymatic action of tri-o-thymotide clathrates applied to the determination of the absolute configuration of four halohydrins. In: Tetrahedron Letters, 1989, vol. 30, n° 48, p. 6677–6678. doi: 10.1016/S0040-4039(00)70648-4
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ISSN of the journal0040-4039
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