The Synthesis of 1,2,4-Trioxan-5-ones

Jefford, Charles; Currie, Jane; Richardson, Geoffrey David; Rossier, Jean-Claude

doi:10.1002/hlca.19910740612

Scientific article

English

The Synthesis of 1,2,4-Trioxan-5-ones

ContributorsJefford, Charles; Currie, Jane; Richardson, Geoffrey David; Rossier, Jean-Claude

Published inHelvetica Chimica Acta, vol. 74, no. 6, p. 1239-1246

Publication date1991

Abstract

Several 3,6-substituted 1,2,4-trioxan-5-ones have been prepared in good yield by condensing aldehydes and ketones with trimethylsilyl α-[(trimethylsilyl)peroxy]alkanoates in the presence of trimethylsilyl trifluoromethane sulfonate as catalyst.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Funding

Swiss National Science Foundation - 20-27966.89

Citation (ISO format)

JEFFORD, Charles et al. The Synthesis of 1,2,4-Trioxan-5-ones. In: Helvetica Chimica Acta, 1991, vol. 74, n° 6, p. 1239–1246. doi: 10.1002/hlca.19910740612

Article (Published version)

Identifiers

PID : unige:152521
DOI : 10.1002/hlca.19910740612

Additional URL for this publicationhttp://doi.wiley.com/10.1002/hlca.19910740612

Journal ISSN0018-019X

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The Synthesis of 1,2,4-Trioxan-5-ones

Several 3,6-substituted 1,2,4-trioxan-5-ones have been prepared in good yield by condensing aldehydes and ketones with trimethylsilyl α-[(trimethylsilyl)peroxy]alkanoates in the presence of trimethylsilyl trifluoromethane sulfonate as catalyst.

Technical informations