Direct Syntheses of Polyfused Ring Systems by Intramolecular Tandem Palladium-Ene/Heck Insertion Reactions

Von Oppolzer, Wolfgang; De Vita, Robert

doi:10.1021/jo00022a004

Scientific article

English

Direct Syntheses of Polyfused Ring Systems by Intramolecular Tandem Palladium-Ene/Heck Insertion Reactions

ContributorsVon Oppolzer, Wolfgang; De Vita, Robert

Published inJournal of Organic Chemistry, vol. 56, no. 22, p. 6256-6257

Publication date1991

Abstract

The Pd(0)-catalyzed polycyclizations 1 → 3 + 4, 5 → 9 and 6 → 10 are described. The stereospecifity of these transformations is ascribed to an intramolecular suprafacial “palladium-ene” process followed by one to two “Heck-insertions” proceeding with retention of configuration at the metalated carbon.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

VON OPPOLZER, Wolfgang, DE VITA, Robert. Direct Syntheses of Polyfused Ring Systems by Intramolecular Tandem Palladium-Ene/Heck Insertion Reactions. In: Journal of Organic Chemistry, 1991, vol. 56, n° 22, p. 6256–6257. doi: 10.1021/jo00022a004

Article (Published version)

Identifiers

PID : unige:152515
DOI : 10.1021/jo00022a004

Additional URL for this publicationhttps://pubs.acs.org/doi/abs/10.1021/jo00022a004

Journal ISSN0022-3263

183views

0downloads

Creation22/06/2021 12:25:00

First validation22/06/2021 12:25:00

Update time16/03/2023 00:46:47

Status update16/03/2023 00:46:46

Last indexation31/10/2024 22:23:22

Archive ouverte UNIGE

Direct Syntheses of Polyfused Ring Systems by Intramolecular Tandem Palladium-Ene/Heck Insertion Reactions

Technical informations