On the Decomposition of 1,2,4-Trioxan-5-ones

Jefford, Charles; Vicente, Maria Da Graca Henriques

doi:10.3987/COM-93-S(T)141

Scientific article

English

On the Decomposition of 1,2,4-Trioxan-5-ones

ContributorsJefford, Charles; Vicente, Maria Da Graca Henriques

Published inHeterocycles, vol. 35, no. 2, p. 725-729

Publication date1993

Abstract

The thermal and chemical properties of six 3,6-substituted 1,2,4-trioxan-5-ones were studied by flash-vacuum thermolysis (FVT) and by treatment with electron-transfer agents. The 1,2,4-trioxan-5-ones exhibited unusual stability both chemically and thermally, but eventually underwent decomposition with loss of carbon dioxide yielding the carbonyl components.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Funding

Swiss National Science Foundation - 20-32'166.91

Citation (ISO format)

JEFFORD, Charles, VICENTE, Maria Da Graca Henriques. On the Decomposition of 1,2,4-Trioxan-5-ones. In: Heterocycles, 1993, vol. 35, n° 2, p. 725–729. doi: 10.3987/COM-93-S(T)141

Article (Published version)

Identifiers

PID : unige:152040
DOI : 10.3987/COM-93-S(T)141

Additional URL for this publicationhttp://www.heterocycles.jp/library/abstract.php?doi=05346

Journal ISSN0385-5414

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On the Decomposition of 1,2,4-Trioxan-5-ones

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