Highly efficient desymmetrisation of a tricarbonylchromium 1,4-dibromonaphthalene complex by asymmetric Suzuki–Miyaura coupling

Urbaneja Biosca, Xavier; Mercier, Audrey Catherine Marie; Besnard, Céline; Kundig, Ernst Peter

doi:10.1039/c1cc10347d

Scientific article

English

Highly efficient desymmetrisation of a tricarbonylchromium 1,4-dibromonaphthalene complex by asymmetric Suzuki–Miyaura coupling

ContributorsUrbaneja Biosca, Xavier; Mercier, Audrey Catherine Marie; Besnard, Céline; Kundig, Ernst Peter

Published inChemical communications, vol. 47, no. 13, p. 3739-3741

Publication date2011

Abstract

Access to planar chiral complexes has been sought by catalytic desymmetrisation of a prochiral complex via asymmetric Suzuki–Miyaura cross-coupling. High selectivities of up to 98% ee were achieved using a bulky chiral palladium catalyst.

Affiliation

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

URBANEJA BIOSCA, Xavier et al. Highly efficient desymmetrisation of a tricarbonylchromium 1,4-dibromonaphthalene complex by asymmetric Suzuki–Miyaura coupling. In: Chemical communications, 2011, vol. 47, n° 13, p. 3739–3741. doi: 10.1039/c1cc10347d

Article (Published version)

Identifiers

PID : unige:14937
DOI : 10.1039/c1cc10347d

Commercial URLhttp://xlink.rsc.org/?DOI=c1cc10347d

ISSN of the journal1359-7345

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Highly efficient desymmetrisation of a tricarbonylchromium 1,4-dibromonaphthalene complex by asymmetric Suzuki–Miyaura coupling

Access to planar chiral complexes has been sought by catalytic desymmetrisation of a prochiral complex via asymmetric Suzuki–Miyaura cross-coupling. High selectivities of up to 98% ee were achieved using a bulky chiral palladium catalyst.

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