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Titles listAccurate hydrogen-bonding energies between 1-naphthol and water, methanol and ammonia
Titles listAccurate hydrogen-bonding energies between 1-naphthol and water, methanol and ammonia
Scientific Article
unige:14811 
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Accurate hydrogen-bonding energies between 1-naphthol and water, methanol and ammonia |
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| Published in | Chemical Physics Letters. 1995, vol. 246, no. 3, p. 291 - 299 | |
| Abstract | Accurate hydrogen-bond dissociation energies were determined for gas-phase hydrogen-bonded complexes between 1-naphthol or 1-naphthol-d3 and H2O, CH3OH, NH3 and ND3, using the stimulated emission pumping-resonant two-photon ionization spectroscopy technique in supersonic jets. The hydrogen-bond dissociation energies obtained for the electronic ground state are D0 = 2035 ± 69 cm−1 for 1-naphthol · H2O, 2645 ± 136 cm−1 for 1-naphthol · CH3OH, 2680 ± 5cm −1 for 1-naphthol · NH3 and 2801 ± 14 cm−1 for 1-naphthol-d3 · ND3, respectively. Upon electronic excitation to the S1 state the binding energies increase by approximately 8%. | |
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Article (Published version) (844 Kb) - Limited access to UNIGE Other version: http://linkinghub.elsevier.com/retrieve/pii/000926149501107K |
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| Citation (ISO format) | BUERGI, Thomas, DROZ, Thierry, LEUTWYLER, Samuel. Accurate hydrogen-bonding energies between 1-naphthol and water, methanol and ammonia. In: Chemical Physics Letters, 1995, vol. 246, n° 3, p. 291 - 299. https://archive-ouverte.unige.ch/unige:14811 |
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