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unige:14721 
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The cis-[RuII(bpy)2(H2O)2]2+ Water-Oxidation Catalyst Revisited |
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| Published in | Angewandte Chemie: International Edition. 2010, vol. 49, no. 42, p. 7745-7747 | |
| Abstract | The only operating mechanism in the oxidation of water to dioxygen catalyzed by the mononuclear cis-[RuII(bpy)2(H2O)2]2+ complex when treated with excess CeIV was unambiguously established. Theoretical calculations together with 18O-labeling experiments (see plot) revealed that it is the nucleophilic attack of water on a Ru=O group. | |
| Keywords | Density functional calculations — Energy conversion — Reaction mechanisms — Ruthenium — Water oxidation | |
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| Citation (ISO format) | SALA, Xavier et al. The cis-[RuII(bpy)2(H2O)2]2+ Water-Oxidation Catalyst Revisited. In: Angewandte Chemie: International Edition, 2010, vol. 49, n° 42, p. 7745-7747. https://archive-ouverte.unige.ch/unige:14721 |
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