UNIGE document Scientific Article
previous document  unige:14721  next document
add to browser collection

The cis-[RuII(bpy)2(H2O)2]2+ Water-Oxidation Catalyst Revisited

Sala, Xavier
Ertem, Mehmed Z.
Vigara, Laura
Todorova, Tanya K.
Chen, Weizhong
Rocha, Reginaldo C.
Cramer, Christopher J.
show hidden authors show all authors [1 - 10]
Published in Angewandte Chemie. 2010, vol. 49, no. 42, p. 7745-7747
Abstract The only operating mechanism in the oxidation of water to dioxygen catalyzed by the mononuclear cis-[RuII(bpy)2(H2O)2]2+ complex when treated with excess CeIV was unambiguously established. Theoretical calculations together with 18O-labeling experiments (see plot) revealed that it is the nucleophilic attack of water on a Ru=O group.
Keywords Density functional calculationsEnergy conversionReaction mechanismsRutheniumWater oxidation
Full text
Article - document accessible for UNIGE members only Limited access to UNIGE
(ISO format)
SALA, Xavier et al. The cis-[RuII(bpy)2(H2O)2]2+ Water-Oxidation Catalyst Revisited. In: Angewandte Chemie, 2010, vol. 49, n° 42, p. 7745-7747. doi: 10.1002/anie.201002398 https://archive-ouverte.unige.ch/unige:14721

629 hits

0 download


Deposited on : 2011-03-18

Export document
Format :
Citation style :