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Significant variation of the singlet-quintet intersystem crossing rate constant in an iron(II) high-spin complex as a function of temperature

Bronisz, Robert
Published in Angewandte Chemie. 2010, vol. 49, no. 45, p. 8509-8512
Abstract In the dilute mixed-crystal system [Zn1−xFex(bbtr)3](ClO4)2, x=2 % (bbtr=1,4-di(1,2,3-triazol-1-yl)butane), the iron(II) centers are predominantly in the high-spin state. The low-spin state can be populated as a metastable state by irradiation with near-IR light; the rate constant of the low-spin→high-spin relaxation spans 14 orders of magnitude between 40 and 220 K
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Deposited on : 2011-03-18

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