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Scientific article
English

Significant variation of the singlet-quintet intersystem crossing rate constant in an iron(II) high-spin complex as a function of temperature

Contributors

Krivokapic, Itana; Chakraborty, Pradip; Bronisz, Robert; Enachescu, Cristian; Hauser, Andreas

Published in

Angewandte Chemie, vol. 49, no. 45, p. 8509-8512

Publication date

2010

Abstract

In the dilute mixed-crystal system [Zn1−xFex(bbtr)3](ClO4)2, x=2 % (bbtr=1,4-di(1,2,3-triazol-1-yl)butane), the iron(II) centers are predominantly in the high-spin state. The low-spin state can be populated as a metastable state by irradiation with near-IR light; the rate constant of the low-spin→high-spin relaxation spans 14 orders of magnitude between 40 and 220 K

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Citation (ISO format)

KRIVOKAPIC, Itana et al. Significant variation of the singlet-quintet intersystem crossing rate constant in an iron(II) high-spin complex as a function of temperature. In: Angewandte Chemie, 2010, vol. 49, n° 45, p. 8509–8512. doi: 10.1002/anie.201004500

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Additional URL for this publication

http://onlinelibrary.wiley.com/store/10.1002/anie.201004500/asset/8509_ftp.pdf?v=1&t=gj1ggxur&s=1601fd1f00e925bba81ace4494d5add738e1f201

Journal ISSN

0044-8249
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Technical informations

Creation

18/03/2011 13:57:07

First validation

18/03/2011 13:57:07

Update

14/03/2023 16:13:57

Status update

14/03/2023 16:13:57

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