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Enantioselective alkylidenecyclopropanation of norbornenes with terminal alkynes catalyzed by palladium–phosphinous acid complexes

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Gatineau, David
Naubron, Jean-Valère
Giordano, Laurent
Buono, Gérard
Published in Tetrahedron: Asymmetry. 2009, vol. 20, no. 16, p. 1912-1917
Abstract Pd(II)-coordinated phosphinous acids catalyzed the formal enantioselective [2+1] cycloaddition of norbornene derivatives with terminal alkynes. The absolute configuration of (+)-3aa was assigned using VCD.
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GATINEAU, David et al. Enantioselective alkylidenecyclopropanation of norbornenes with terminal alkynes catalyzed by palladium–phosphinous acid complexes. In: Tetrahedron: Asymmetry, 2009, vol. 20, n° 16, p. 1912-1917. https://archive-ouverte.unige.ch/unige:14704

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Deposited on : 2011-03-18

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