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First emission studies of Tc2X82- systems (X = Cl, Br)

Briggs, Breeze N.
McMillin, David R.
Todorova, Tanya K.
Poineau, Frederic
Czerwinski, Kenneth R.
Sattelberger, Alfred P.
Published in Dalton Transactions. 2010, vol. 39, p. 11322-11324
Abstract The emission spectra of the solids [n-Bu4N]2Tc2X8 (X = Cl, Br) have been investigated at room temperature and 77 K. In each case, the emission originates in the 1δ–δ* excited state, as with the rhenium homologues, but has a shorter lifetime.
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BRIGGS, Breeze N. et al. First emission studies of Tc2X82- systems (X = Cl, Br). In: Dalton Transactions, 2010, vol. 39, p. 11322-11324. https://archive-ouverte.unige.ch/unige:14694

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Deposited on : 2011-03-18

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