First emission studies of Tc2X82- systems (X = Cl, Br)

Briggs, Breeze N.; McMillin, David R.; Todorova, Tanya K.; Gagliardi, Laura; Poineau, Frederic; Czerwinski, Kenneth R.; Sattelberger, Alfred P.

doi:10.1039/C0DT00751J

Scientific article

English

First emission studies of Tc2X82- systems (X = Cl, Br)

ContributorsBriggs, Breeze N.; McMillin, David R.; Todorova, Tanya K.; Gagliardi, Laura; Poineau, Frederic; Czerwinski, Kenneth R.; Sattelberger, Alfred P.

Published inDalton transactions, vol. 39, p. 11322-11324

Publication date2010

Abstract

The emission spectra of the solids [n-Bu4N]2Tc2X8 (X = Cl, Br) have been investigated at room temperature and 77 K. In each case, the emission originates in the 1δ–δ* excited state, as with the rhenium homologues, but has a shorter lifetime.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie physique

Citation (ISO format)

BRIGGS, Breeze N. et al. First emission studies of Tc2X82- systems (X = Cl, Br). In: Dalton transactions, 2010, vol. 39, p. 11322–11324. doi: 10.1039/C0DT00751J

Article

Identifiers

PID : unige:14694
DOI : 10.1039/C0DT00751J

Additional URL for this publicationhttp://pubs.rsc.org/en/Content/ArticlePDF/2010/DT/C0DT00751J

Journal ISSN1477-9226

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First emission studies of Tc2X82- systems (X = Cl, Br)

The emission spectra of the solids [n-Bu4N]2Tc2X8 (X = Cl, Br) have been investigated at room temperature and 77 K. In each case, the emission originates in the 1δ–δ* excited state, as with the rhenium homologues, but has a shorter lifetime.

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