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Scientific article
English

Origin of rate acceleration in enantioselective hydrogenation of a-functionalised ketones over cinchona alkaloid modified platinum

Published inNew journal of chemistry, vol. 26, p. 807-810
Publication date2002
Abstract

The origin of the rate acceleration in enantioselective hydrogenation of α-functionalised ketones over cinchona alkaloid modified platinum has been studied using a combined experimental and theoretical approach, and the rate acceleration is traced to a lowering of the energy of the carbonyl Π orbitals in the diastereomeric complex formed between reactant and modifier.

Citation (ISO format)
VARGAS, Angelo, BUERGI, Thomas, BAIKER, Alfons. Origin of rate acceleration in enantioselective hydrogenation of a-functionalised ketones over cinchona alkaloid modified platinum. In: New journal of chemistry, 2002, vol. 26, p. 807–810. doi: 10.1039/b202182j
Identifiers
ISSN of the journal1144-0546
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