UNIGE document Scientific Article
previous document  unige:14660  next document
add to browser collection
Title

Light-induced excited spin state trapping (LIESST) in [Fe(2-mephen)3]2+ embedded in polymer matrices

Authors
Adler, Jürgen
Gütlich, Philipp
Published in Chemical Physics Letters. 1988, vol. 152, no. 6, p. 468-472
Abstract It is known that [Fe (2-mephen)3] (ClO4)2 in the solid state is an iron(II) spin-crossover system which shows light-induced excited spin state trapping (LIESST). The thermal spin-crossover behaviour of the complex [Fe(2-mephen)3]2+ embedded in various polymer matrices is similar to the solid-state behaviour, and a light-induced long-lived excited state is observed at temperatures below 50 K. Relaxation curves show that polymer matrices are not very homogeneous media.
Identifiers
Full text
Structures
Citation
(ISO format)
HAUSER, Andreas, ADLER, Jürgen, GÜTLICH, Philipp. Light-induced excited spin state trapping (LIESST) in [Fe(2-mephen)3]2+ embedded in polymer matrices. In: Chemical Physics Letters, 1988, vol. 152, n° 6, p. 468-472. https://archive-ouverte.unige.ch/unige:14660

226 hits

0 download

Update

Deposited on : 2011-03-18

Export document
Format :
Citation style :