UNIGE document Scientific Article
previous document  unige:14643  next document
add to browser collection

Ground state binding energy and vibrations of the carbazole·Ar van der Waals complex by pump/dump-R2PI measurements

Droz, Thierry
Leutwyler, Samuel
Published in Chemical Physics Letters. 1994, vol. 225, no. 4-6, p. 351-358
Abstract Mass-selective ground state vibrational spectroscopy of the jet-cooled carbazole·Ar complex was performed by populating ground-state levels via a pump/dump laser pulse sequence, followed by selective resonant two-photon ionization of the vibrationally relaxed complexes. Intra- and inter-molecular van der Waals modes in the S0 state are measurable with good signal/noise. The ground-state binding energy can be determined by detecting the negative signals resulting from loss of ground-state population via vibrational predissociation of the complex.
Stable URL https://archive-ouverte.unige.ch/unige:14643
Full text

209 hits

0 download


Deposited on : 2011-03-18

Export document
Format :
Citation style :