Metallomesogens with extended bent tridentate receptors: columnar and cubic mesomorphism tuned by the size of the lanthanide metal ions

Terazzi, Emmanuel; Benech, Jean-Marc; Rivera, Jean-Pierre; Bernardinelli, Gérald Hugues; Donnio, Bertrand; Guillon, Daniel; Piguet, Claude

doi:10.1039/b211902a

Scientific article

English

Metallomesogens with extended bent tridentate receptors: columnar and cubic mesomorphism tuned by the size of the lanthanide metal ions

ContributorsTerazzi, Emmanuel; Benech, Jean-Marc; Rivera, Jean-Pierre; Bernardinelli, Gérald Hugues; Donnio, Bertrand; Guillon, Daniel; Piguet, Claude

Published inDalton Transactions, no. 5, p. 769-772

Publication date2003

Abstract

The increase of the curvature of the interface between the rigid mesogenic core and the aliphatic chains in the hexacatenar tridentate ligand L3 overcomes the considerable expansion brought by the complexation of bulky metallic cores, thus leading to organized cubic mesophases for monometallic zincII and lanthanideIII complexes.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie minérale, analytique et appliquée

Citation (ISO format)

TERAZZI, Emmanuel et al. Metallomesogens with extended bent tridentate receptors: columnar and cubic mesomorphism tuned by the size of the lanthanide metal ions. In: Dalton Transactions, 2003, n° 5, p. 769–772. doi: 10.1039/b211902a

Article (Published version)

Identifiers

PID : unige:146049
DOI : 10.1039/b211902a

Additional URL for this publicationhttp://xlink.rsc.org/?DOI=b211902a

Journal ISSN1477-9226

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Metallomesogens with extended bent tridentate receptors: columnar and cubic mesomorphism tuned by the size of the lanthanide metal ions

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