UNIGE document Scientific Article
previous document  unige:14468  next document
add to browser collection
Title

Identification of a Valuable Kinetic Process in Copper-Catalyzed Asymmetric Allylic Alkylation

Authors
Published in Angewandte Chemie: International Edition. 2011, vol. 50, no. 8, p. 1877 - 1881
Abstract Copper bottomed: The application of a previously described process of dynamic kinetic asymmetric transformation to acyclic substrates allowed the identification of a relevant kinetic process in the title reaction (see scheme; CuTC= copper(I) thiophencarboxylate, Naphth= naphthyl). The optimization of the reaction conditions and generality of the method, as well as mechanistic considerations are disclosed.
Keywords AlkylationAllylic compoundsAsymmetric catalysisCopperGrignard reagents
Identifiers
Full text
Article (Published version) (378 Kb) - document accessible for UNIGE members only Limited access to UNIGE
Other version: http://doi.wiley.com/10.1002/anie.201005373
Structures
Citation
(ISO format)
LANGLOIS, Jean-Baptiste, ALEXAKIS, Alexandre. Identification of a Valuable Kinetic Process in Copper-Catalyzed Asymmetric Allylic Alkylation. In: Angewandte Chemie: International Edition, 2011, vol. 50, n° 8, p. 1877 - 1881. https://archive-ouverte.unige.ch/unige:14468

203 hits

4 downloads

Update

Deposited on : 2011-02-18

Export document
Format :
Citation style :