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Title

Identification of a Valuable Kinetic Process in Copper-Catalyzed Asymmetric Allylic Alkylation

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Published in Angewandte Chemie: International Edition. 2011, vol. 50, no. 8, p. 1877 - 1881
Abstract Copper bottomed: The application of a previously described process of dynamic kinetic asymmetric transformation to acyclic substrates allowed the identification of a relevant kinetic process in the title reaction (see scheme; CuTC= copper(I) thiophencarboxylate, Naphth= naphthyl). The optimization of the reaction conditions and generality of the method, as well as mechanistic considerations are disclosed.
Keywords AlkylationAllylic compoundsAsymmetric catalysisCopperGrignard reagents
Stable URL https://archive-ouverte.unige.ch/unige:14468
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Other version: http://doi.wiley.com/10.1002/anie.201005373
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Deposited on : 2011-02-18

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