Evidence of ionic liquid crystal properties for a DODA+ salt of the keplerate [Mo132O372(CH3COO)30(H2O)72]42−

Floquet, Sébastien; Terazzi, Emmanuel; Hijazi, Akram; Guenee, Laure; Piguet, Claude; Cadot, Emmanuel

doi:10.1039/c2nj20923c

Scientific article

Letter

English

Evidence of ionic liquid crystal properties for a DODA⁺ salt of the keplerate [Mo₁₃₂O₃₇₂(CH₃COO)₃₀(H₂O)₇₂]⁴²⁻

ContributorsFloquet, Sébastien; Terazzi, Emmanuel; Hijazi, Akram; Guenee, Laure; Piguet, Claude

; Cadot, Emmanuel

Published inNew Journal of Chemistry, vol. 36, no. 4, p. 865-868

Publication date2012

Abstract

Thermal studies of a DODA+ salt of the nanoscopic hollow sphere [Mo132O372(H2O)72(CH3CO2)30]42− revealed ionic liquid crystalline properties, which were evidenced by Polarised Optical Microscopy, DSC and SA-XRD.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie minérale, analytique et appliquée

Citation (ISO format)

FLOQUET, Sébastien et al. Evidence of ionic liquid crystal properties for a DODA⁺ salt of the keplerate [Mo₁₃₂O₃₇₂(CH₃COO)₃₀(H₂O)₇₂]⁴²⁻. In: New Journal of Chemistry, 2012, vol. 36, n° 4, p. 865–868. doi: 10.1039/c2nj20923c

Article (Published version)

Identifiers

PID : unige:144412
DOI : 10.1039/c2nj20923c

Additional URL for this publicationhttp://xlink.rsc.org/?DOI=c2nj20923c

Journal ISSN1144-0546

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Evidence of ionic liquid crystal properties for a DODA+ salt of the keplerate [Mo132O372(CH3COO)30(H2O)72]42−

Thermal studies of a DODA+ salt of the nanoscopic hollow sphere [Mo132O372(H2O)72(CH3CO2)30]42− revealed ionic liquid crystalline properties, which were evidenced by Polarised Optical Microscopy, DSC and SA-XRD.

Technical informations

Evidence of ionic liquid crystal properties for a DODA⁺ salt of the keplerate [Mo₁₃₂O₃₇₂(CH₃COO)₃₀(H₂O)₇₂]⁴²⁻