

Other version: http://xlink.rsc.org/?DOI=D0OB01809K
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Synthesis and properties of chiral fluorescent helicene-BODIPY conjugates |
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Published in | Organic & biomolecular chemistry. 2020, vol. 18, no. 38, p. 7677-7684 | |
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Synthetic methodology in OBC |
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Abstract | A series of chiral fluorescent helicene-BODIPY conjugates was prepared by the regioselective formylation of aza[4]helicene precursors and then an efficient one-pot two-step BODIPY synthesis (13 examples, 28–82%). Fused conjugates exhibit absorption and fluorescence properties (ΦF 30–45%) in the red visible domain, and a CPL signature could be measured at 605 nm (glum ±5 × 10⁻⁴). Photophysical and electronic properties were investigated and rationalized through first principles. | |
Identifiers | DOI: 10.1039/D0OB01809K | |
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![]() ![]() Other version: http://xlink.rsc.org/?DOI=D0OB01809K |
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Research group | Groupe Lacour | |
Projects | Swiss National Science Foundation: 200020_172497 Swiss National Science Foundation: 200020_184843 | |
Citation (ISO format) | MONEVA LORENTE, Pau et al. Synthesis and properties of chiral fluorescent helicene-BODIPY conjugates. In: Organic and Biomolecular Chemistry, 2020, vol. 18, n° 38, p. 7677-7684. doi: 10.1039/D0OB01809K https://archive-ouverte.unige.ch/unige:142591 |