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Data analysis in transient electronic spectroscopy – an experimentalist's view

Contributors

Beckwith, Joseph; Rumble, Christopher Allen; Vauthey, Eric

Published in

International Reviews in Physical Chemistry, vol. 39, no. 2, p. 135-216

Publication date

2020

Abstract

Time-resolved electronic spectroscopy has grown into a technique that provides hundreds to thousands of electronic spectra with femtosecond time resolution. This enables complex questions to be interrogated, with an obvious cost that the data are more detailed and thus require accurate modelling to be properly reproduced. Analysis of these data comes in a variety of forms, starting with a variety of assumptions about how the data may be decomposed. Here, four different types of analysis commonly used are discussed: band-shape analysis, global kinetic analysis, lifetime distribution models, and soft-modelling. This review provides a ?user's guide? to these various methods of data analysis, and attempts to elucidate their successes, domains in which they may be useful, and potential pitfalls in their usage.

UNIGE affiliation entities

UNIGE research groups

Funding

  • Swiss National Science Foundation - 00020-184607

Citation (ISO format)

BECKWITH, Joseph, RUMBLE, Christopher Allen, VAUTHEY, Eric. Data analysis in transient electronic spectroscopy – an experimentalist’s view. In: International Reviews in Physical Chemistry, 2020, vol. 39, n° 2, p. 135–216. doi: 10.1080/0144235X.2020.1757942

Main files (1)

Article (Accepted version)

Identifiers

Additional URL for this publication

https://www.tandfonline.com/doi/full/10.1080/0144235X.2020.1757942

Journal ISSN

0144-235X
614views
1889downloads

Technical informations

Creation

18/06/2020 15:40:00

First validation

18/06/2020 15:40:00

Update

15/03/2023 22:10:40

Status update

15/03/2023 22:10:40

Last indexation

31/10/2024 19:01:25
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