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Mechanosensitive membrane probes: push-pull papillons

Published in Supramolecular Chemistry. 2020, vol. 32, no. 2, p. 106-111
Abstract Design, synthesis and evaluation of push-pull N,N′-diphenyl-dihydrodibenzo[a,c]phenazines are reported. Consistent with theoretical predictions, donors and acceptors attached to the bent mechanophore are shown to shift absorption maxima to either red or blue, depending on their positioning in the chromophore. Redshifted excitation of push-pull fluorophores is reflected in redshifted emission of both bent and planar excited states. The intensity ratios of the dual emission in more and less polar solvents imply that excited-state (ES) planarization decelerates with increasing fluorophore macrodipole, presumably due to attraction between the wings of closed papillons. ES planarization of highly polarisable papillons is not observed in lipid bilayer membranes. All push-pull papillon amphiphiles excel with aggregation-induced emission (AIE) from bent ES as micelles in water and mechanosensitivity in viscous solvents. They are not solvatochromic and only weakly fluorescent (QY < 4%).
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Research groups Groupe Matile
Groupe Vauthey
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HUMENIUK, Heorhii et al. Mechanosensitive membrane probes: push-pull papillons. In: Supramolecular Chemistry, 2020, vol. 32, n° 2, p. 106-111. doi: 10.1080/10610278.2019.1702193 https://archive-ouverte.unige.ch/unige:131618

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Deposited on : 2020-03-02

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