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Scientific article
Open access
English

A Chiral and Colorful Redox Switch: Enhanced π Acidity in Action

Published inAngewandte Chemie, vol. 49, no. 42, p. 7680-7683
Publication date2010
Abstract

Deep blue diving: π Acidities up to a new record of −4.74 eV are made possible with simple sulfur redox chemistry (see scheme). This attractive method is able to generate exceptional electron affinities and anion transport efficiencies for applications in optoelectronic devices, medicinal chemistry, and anion–π catalysis.

Keywords
  • Anion–π interactions
  • Chirality
  • Ion transport
  • Molecular switches
  • π acidity
Citation (ISO format)
MISEK, Jiri et al. A Chiral and Colorful Redox Switch: Enhanced π Acidity in Action. In: Angewandte Chemie, 2010, vol. 49, n° 42, p. 7680–7683. doi: 10.1002/anie.201003722
Main files (2)
Article (Published version)
accessLevelRestricted
Article (Accepted version)
Identifiers
ISSN of the journal1433-7851
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171downloads

Technical informations

Creation10/08/2010 4:38:00 PM
First validation10/08/2010 4:38:00 PM
Update time03/14/2023 4:07:23 PM
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