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Scientific article
English

Chiral hexacoordinated phosphates: From pioneering studies to modern uses in stereochemistry

ContributorsLacour, Jérôme
Published inComptes rendus. Chimie, vol. 13, no. 8-9, p. 985-997
Publication date2010
Abstract

Chiral cationic molecular structures and supramolecular assemblies can be effectively analyzed, resolved and stereocontrolled through an asymmetric ion pairing with enantiopure hexacoordinated phosphate anions like TRISPHAT or BINPHAT. After an historical perspective on the development of these anionic reagents, this account describes their synthesis and their use as chiral NMR solvating, resolving and asymmetry-inducing reagents.

Keywords
  • Hexacoordinated phosphorus
  • Asymmetric ion pairing
  • Chiral anion
  • NMR enantiodifferentiation
  • Resolution
  • Supramolecular stereocontrol
Citation (ISO format)
LACOUR, Jérôme. Chiral hexacoordinated phosphates: From pioneering studies to modern uses in stereochemistry. In: Comptes rendus. Chimie, 2010, vol. 13, n° 8-9, p. 985–997. doi: 10.1016/j.crci.2010.02.009
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ISSN of the journal1631-0748
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Creation09/17/2010 10:42:00 AM
First validation09/17/2010 10:42:00 AM
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