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Title

Versatile heteroleptic bis-terdentate Cr(III) chromophores displaying room temperature millisecond excited state lifetimes

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Published in Chemical Communications. 2018, vol. 54, no. 94, p. 13228-13231
Abstract Substitution of Ru(II)‐based chromophores with cheaper Cr(III)‐ based complexes in optically active metallo‐supramolecular architectures is limited by the lack of synthetic strategies leading to heteroleptic Cr(III)‐polypyridyl complexes with long excitedstate lifetimes. Herein, we report on a versatile method yielding heteroleptic bis(terdentate) Cr(III) complexes with room temperature millisecond range excited‐state lifetimes, tuneable electronic and photophysical properties and easy anchoring possibilities.
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Other version: http://xlink.rsc.org/?DOI=C8CC07671E
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Research group Groupe Piguet
Project FNS: 200020_178758
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JIMENEZ, Juan et al. Versatile heteroleptic bis-terdentate Cr(III) chromophores displaying room temperature millisecond excited state lifetimes. In: Chemical Communications, 2018, vol. 54, n° 94, p. 13228-13231. doi: 10.1039/C8CC07671E https://archive-ouverte.unige.ch/unige:111464

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Deposited on : 2018-11-27

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