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Title

On-line identification of further flavoneC- and O-glycosides from sugarcane (Saccharum officinarum L., Gramineae) by HPLC-UV-MS

Authors
Colombo, Renata
Yariwake, Janete H.
Queiroz, Emerson F.
Published in Phytochemical Analysis. 2006, vol. 17, no. 5, p. 337 - 343
Abstract HPLC-UV-MS (APCI-MS/MS and CID/MS) was utilised for the identification of eight additional flavone glycosides from sugarcane (Saccharum officinarum L., Gramineae) extracts of bagasse, leaves and juice ('garapa'). Relevant information about substitution patterns was obtained through UV detection using post-column addition of shift reagents, while tandem MS provided structural information confirming the proposed structures of the C-glycosides vitexin, orientin, luteolin-8-C-(rhamnosylglucoside), 4',5'-dimethyl-luteolin-8-C-glycoside and the isomeric pair schaftoside-isoschaftoside, besides the O-glycosides tricin-7-O-neohesperidoside and tricin-7-O-glycoside.
Keywords LIQUID-CHROMATOGRAPHYMASS-SPECTROMETRYPLANT-EXTRACTSDERIVATIZATIONSPECTROSCOPYSACCHARUM
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Other version: http://doi.wiley.com/10.1002/pca.923
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COLOMBO, Renata et al. On-line identification of further flavoneC- and O-glycosides from sugarcane (Saccharum officinarum L., Gramineae) by HPLC-UV-MS. In: Phytochemical Analysis, 2006, vol. 17, n° 5, p. 337 - 343. https://archive-ouverte.unige.ch/unige:11024

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Deposited on : 2010-08-27

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