Determination of Hf, Sc and Y in geological samples together with the rare-earth elements

Article Article scientifique Article Determination of Hf, Sc and Y in geological samples together with the rare-earth elements eng 1997 author Lihareva Nadejda Ljubenova 88509 author Delaloye Michel 24865 314-316 10.1007/s002160050159 0937-0633 http://link.springer.com/10.1007/s002160050159 A method is described for the determination of Hf, Sc and Y simultaneously with the REE in geological materials. An earlier method for REE separation from major elements was studied with the aim to apply it also to the determination of Hf, Sc and Y. Sample decomposition was carried out by melting with LiBO2. The method involves separation and concentration stages, using the cation-exchange resin DOWEX AG 50W-X8. Matrix elements were eluted with 2 mol/1 HCl, whereas 6 mol/1 HNO3 with oxalic acid and 8 mol/1 HNO3 were used to elute the elements to be determined. Some of the matrix elements could not be completely removed. This effect as well as the recovery rates of the determined elements were investigated. The measurements were performed by ICP-AES. Spectral interferences were also tested. Dewey 550 Open Access - Licence nationale Springer 42 Département des sciences de la Terre 154 false Fresenius' Journal of Analytical Chemistry 357 3 60c9f85b-bb04-4574-9c81-fc28b638b95b Article (Published version) Public Lihareva-Delaloye1997_Article_DeterminationOfHfScAndYInGeolo.pdf 274973 application/pdf openAccess Faculté des sciences / Section des sciences de la Terre et de l'Environnement / Département des sciences de la Terre

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Determination of Hf, Sc and Y in geological samples together with the rare-earth elements	Fresenius' Journal of Analytical Chemistry			1997	302	212

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Lihareva, Nadejda Ljubenova