Self-organizing surface-initiated polymerization, templated self-sorting and templated stack exchange: synthetic methods to build complex systems

Article Article scientifique Article Self-organizing surface-initiated polymerization, templated self-sorting and templated stack exchange: synthetic methods to build complex systems eng 2013 author Lista Marco 662953 author Orentas Edvinas 735914 author Areephong Jetsuda 715484 author Charbonnaz Pierre 631649 author Wilson Adam 778574 author Zhao Yingjie 757219 author Bolag Alatengbaolige 788201 author Sforazzini Giuseppe 754091 author Turdean Raluca 768196 author Hayashi Hironobu 771229 author Domoto Yuya 744959 author Sobczuk Adam Antoni 771151 author Sakai Naomi 0000-0002-9460-1944 131140 author Matile Stefan 0000-0002-8537-8349 129654 1754-1765 10.1039/c3ob27303b 1477-0520 http://xlink.rsc.org/?DOI=c3ob27303b In nature, spectacular function is achieved by highly sophisticated supramolecular architectures. Little is known what we would obtain if we could create complexity with similar precision, because the synthetic methods to do so are not available. This account summarizes recent approaches conceived to improve on this situation. With self-organizing surface-initiated polymerization (SOSIP), charge-transporting stacks can be grown directly on solid substrates with molecular-level precision. The extension to templated self-sorting (SOSIP-TSS) offers a supramolecular approach to multicomponent architectures. A solid theoretical framework for the transcription of information by templated self-sorting has been introduced, intrinsic templation efficiencies up to 97% have been achieved, and the existence of self-repair has been shown. The extension to templated stack exchange (SOSIP-TSE) offers the complementary covalent approach. Compatibility of this robust method with the creation of double-channel architectures with antiparallel two-component gradients has been demonstrated. Dewey 540 36 Département de chimie organique 141 false Organic & biomolecular chemistry 11 11 112baac2-1512-4b4c-98a0-1a97da6ae27a Article (Published version) Restricted c3ob27303b.pdf 5187207 application/pdf 40af8f0b-f0e2-4161-a3d9-802fac5a80d8 Article (Accepted version) Public 201.pdf 2507157 application/pdf OA OTHER openAccess Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Title	Published in	Year	Views	Downloads

Antiparallel three-component gradients in double-channel surface architectures	Chemical science	2014	646	1
Self-organizing surface-initiated polymerization, templated self-sorting and templated stack exchange: synthetic methods to build complex systems	Organic & biomolecular chemistry	2013	676	97

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Sobczuk, Adam Antoni