Total Synthesis of (±)-α-Acoradiene via Intramolecular Photoaddition and Reductive Cyclobutane Cleavage

Article Article scientifique Article Total Synthesis of (±)-α-Acoradiene via Intramolecular Photoaddition and Reductive Cyclobutane Cleavage eng 2004-10-25 1983-03-16 author Von Oppolzer Wolfgang 25270 author Zutterman Freddy G.-A. 71930 author Bättig Kurt 522-533 10.1002/hlca.19830660213 0018-019X https://onlinelibrary.wiley.com/doi/10.1002/hlca.19830660213 (±)-α-Acoradiene (4) has been synthesized from 3-methoxy-2-cyclohexenone by a sequence of 8 steps. The key steps (Scheme 6) are the regio- and stereoselective photo[2+2]addition 7→6 and the reductive fragmentation 6→5. Dewey 540 36 Département de chimie organique 141 false Helvetica chimica acta 66 2 9d50a183-ac83-426f-adc1-42f4478e1fd6 Article (Published version) Restricted Oppolzer_HCA_198366522.pdf 764171 application/pdf 65b4dab65c577f2adfdb120a9af974aeb7f324b6077960b302c7a2c9b1a8de41 restrictedAccess Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

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Total Synthesis of (±)-α-Acoradiene via Intramolecular Photoaddition and Reductive Cyclobutane Cleavage	Helvetica chimica acta			1983	75	0

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Zutterman, Freddy G.-A.