Photoinduced Symmetry-Breaking Charge Separation: The Direction of the Charge Transfer

Article Article scientifique Article Photoinduced Symmetry-Breaking Charge Separation: The Direction of the Charge Transfer eng 2011 author Markovic Vesna 680663 author Villamaina Diego 697535 author Barabanov Igor Ivanovitch 629901 author Lawson Daku Latevi Max 530149 author Vauthey Eric 0000-0002-9580-9683 133895 7596-7598 10.1002/anie.201102601 1433-7851 Even flow: Photoinduced symmetry-breaking charge separation takes place in a few picoseconds in a 1,3-bis(perylene)propane dyad in polar solvents. Polarized transient absorption measurements show that the direction of the charge flow is random and entirely governed by the fluctuations of the solvent orientation around the dyad. Dewey 540 38 Département de chimie physique 142 false 686 Groupe Vauthey Angewandte Chemie 50 33 2e36b63b-4cb3-4900-8225-4a2802ee7a75 Article (Published version) Public ref01253.pdf 385356 application/pdf openAccess Faculté des sciences / Section de chimie et biochimie / Département de chimie physique

Title	Published in	Access level	OA Policy	Year	Views	Downloads

Photoinduced Symmetry-Breaking Charge Separation: The Direction of the Charge Transfer	Angewandte Chemie			2011	911	755

Archive ouverte UNIGE

Barabanov, Igor Ivanovitch