Enantioselective nucleophilic addition of organometallic reagents to quinoline: regio-, stereo- and enantioselectivity

Article Article scientifique Article Enantioselective nucleophilic addition of organometallic reagents to quinoline: regio-, stereo- and enantioselectivity eng 2004 author Amiot Franck 125628 author Cointeaux Laure 561408 author Silve Emmanuelle Frédérique 504622 author Alexakis Alexandre 123950 8221-8231 10.1016/j.tet.2004.06.088 0040-4020 Some 2-alkyl-1,2-dihydroquinoline and some 2-aryl-1,2-dihydroquinoline were obtained by enantioselective addition of methyl-, butyl-, phenyl- and 1-naphthyllithium on quinoline. Bisoxazolines were used as external chiral ligands, giving enantiomeric excess up to 79%. The ligand could be used in catalytic amounts without significant loss of enantioselectivity. 1,2-Dihydroquinoline Enantioselective addition Chiral ligand Organolithium reagents Organometallics Bioxazoline Dewey 540 36 Département de chimie organique 141 false Tetrahedron 60 37 e7e2c54c-0946-4567-a0b7-f8e26278c239 Article (Published version) Restricted file1.pdf 370992 application/pdf Vignette Public file2.jpg 8468 image/jpeg restrictedAccess Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

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Enantioselective nucleophilic addition of organometallic reagents to quinoline: regio-, stereo- and enantioselectivity	Tetrahedron			2004	603	0

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Silve, Emmanuelle Frédérique