Practical preparation and metallo-ene reactions of (2-alkenylallyl)-magnesium chlorides: comparative study of magnesium activation

Article Article scientifique Lettre Practical preparation and metallo-ene reactions of (2-alkenylallyl)-magnesium chlorides: comparative study of magnesium activation eng 1984 author Von Oppolzer Wolfgang 25270 author Schneider Philippe 31452 3305-3308 10.1016/S0040-4039(01)81370-8 0040-4039 https://linkinghub.elsevier.com/retrieve/pii/S0040403901813708 <p>Magnesium activated by equilibration with its anthracene adduct in THF metalates smoothly 2-alkenyl chlorides at −65°C without significant coupling. The resulting solutions of Grignard reagents are subjected to thermal (80–130°C) cyclization followed by trapping with electrophiles.</p> Dewey 540 36 Département de chimie organique 141 false Tetrahedron letters 25 31 2a23625b-50d4-4857-90e5-7bf2eac27834 Article (Published version) Restricted Oppolzer_TL_1984253305.pdf 1573057 application/pdf e3fdd92793d0434a05a67666e9093305cba0336f8378e212156df6f4da65c67a restrictedAccess Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

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Practical preparation and metallo-ene reactions of (2-alkenylallyl)-magnesium chlorides: comparative study of magnesium activation	Tetrahedron letters			1984	61	0

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Schneider, Philippe