Herboxidiene: Determination of absolute configuration by degradation and synthetic studies

Article Article scientifique Article Herboxidiene: Determination of absolute configuration by degradation and synthetic studies eng 1998-03-26 1997-02-24 author Edmunds A.J.F. author Trueb W. author Von Oppolzer Wolfgang 25270 author Cowley Phillip Martin 30031 2785-2802 10.1016/s0040-4020(97)00021-5 0040-4020 https://linkinghub.elsevier.com/retrieve/pii/S0040402097000215 Degradation of the novel polyketide herbicide herboxidiene leads to useful fragments for further analogue synthesis and also enabled determination of the absolute configuration of the natural product via asymmetric synthesis of the respective fragments. A combination of degradation, and asymmetric synthetic studies enabled the absolute configuration of herboxidiene to be determined. The fragments obtained from degradation are useful for the preparation of semi-synthetic herboxidiene analogues. Dewey 540 36 Département de chimie organique 141 false Tetrahedron 53 8 f8337ce5-ab93-4d3a-8c85-f6eee05d21f3 Article (Published version) Restricted 1-s2.0-S0040402097000215-main.pdf 1118891 application/pdf Vignette Public 1-s2.0-S0040402097000215-gr1.gif 27935 image/gif restrictedAccess Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

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Herboxidiene: Determination of absolute configuration by degradation and synthetic studies	Tetrahedron			1997	175	0

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Cowley, Phillip Martin