Tricarbonylchromium Phenyloxazoline and -Imine Complexes: Highly Regioselective <i>ortho</i>-Additions of Carbon Nucleophiles

Article Article scientifique Article Tricarbonylchromium Phenyloxazoline and -Imine Complexes: Highly Regioselective <i>ortho</i>-Additions of Carbon Nucleophiles eng 1991 author Kundig Ernst Peter 26401 author Amurrio Derpic David 24302 author Liu Rong-Ming 24637 author Ripa Alberto 24172 657-658 10.1055/s-1991-20831 0936-5214 Alkyl-, vinyl- and aryllithium reagents and an ester enolate added efficiently and highly regioselectively ortho to the aromatic substituent of tricarbonyl(4,5-dihydro-4,4-dimethyl-2-phenyloxazole)chromium(0) (1) and tricarbonyl(benzylidene-cyclohexylamine)chromium(0) (2) complexes. The tertiary carbanion 2-lithio-2-methylpropionitrile gave a 3:1 para/meta selectivity. Complex 1 was obtained via arene exchange in tricarbonyl(naphthalene)chromium(0). Dewey 540 36 Département de chimie organique 141 false Synlett 745ba62f-f14f-440e-80af-0cc8aab2c336 Article (Published version) Restricted Kundig_Synlett_1991657.pdf 1669440 application/pdf restrictedAccess Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

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Tricarbonylchromium Phenyloxazoline and -Imine Complexes: Highly Regioselective ortho-Additions of Carbon Nucleophiles	Synlett			1991	515	0

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Amurrio Derpic, David