Interactions of squaric and croconic acids with [PtL4]2+ complexes (L = NH3, L2 = ethylenediamine): oxidative properties of oxocarbon acids and crystal structure determinations

Castan, Paule; Deguenon, Diane; Fabre, Paul-Louis; Bernardinelli, Gérald Hugues

doi:10.1016/S0277-5387(00)83339-2

Scientific article

English

Interactions of squaric and croconic acids with [PtL₄]²⁺ complexes (L = NH₃, L₂ = ethylenediamine): oxidative properties of oxocarbon acids and crystal structure determinations

ContributorsCastan, Paule; Deguenon, Diane; Fabre, Paul-Louis; Bernardinelli, Gérald Hugues

Published inPolyhedron, vol. 11, no. 8, p. 901-908

Publication date1992

Abstract

Squaric (H2Sq) and croconic (H2Croc) acid (H2A) react with [PtL4]2+ (L = ammonia or L2 = ethylenediamine) to yield complexes formulating as [PtL4](HA)2. The crystal structure of the complexes [Pt(en)2](HSq)2 and [Pt(en)2](HCroc)2 have been determined using X-ray diffraction techniques. Oxidation of platinum occurred in the course of the same reaction and complexes of [PtL4Cl2]A were obtained. The X-ray determination of the structure of [Pt(NH3)4Cl2]Sq is reported. Electrochemical measurements have been performed in the solid state to support the results obtained during the oxidation process.

Affiliation

Faculté des sciences / Section de physique

Citation (ISO format)

CASTAN, Paule et al. Interactions of squaric and croconic acids with [PtL4]2+ complexes (L = NH3, L2 = ethylenediamine): oxidative properties of oxocarbon acids and crystal structure determinations. In: Polyhedron, 1992, vol. 11, n° 8, p. 901–908. doi: 10.1016/S0277-5387(00)83339-2

Article (Published version)

Identifiers

PID : unige:91489
DOI : 10.1016/S0277-5387(00)83339-2

Commercial URLhttp://linkinghub.elsevier.com/retrieve/pii/S0277538700833392

ISSN of the journal0277-5387

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Interactions of squaric and croconic acids with [PtL4]2+ complexes (L = NH3, L2 = ethylenediamine): oxidative properties of oxocarbon acids and crystal structure determinations

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Interactions of squaric and croconic acids with [PtL₄]²⁺ complexes (L = NH₃, L₂ = ethylenediamine): oxidative properties of oxocarbon acids and crystal structure determinations